The picture is kind of blurry but I assume it is the dark colored ring that I think I am seeing. How long has the star San been in the air lock? Could be mildew. I don’t use an airlock after the first 2 weeks or so of fermentation on my sour beers. I usually just wrap aluminum foil over the mouth of the glass carboy because the airlock can dry up, it is a potential for oxygen ingress depending on how long you are letting them sit, and star San loses it’s sanitizing abilities over time. I have used star San in a pot that I was using for a swamp cooler and a lot of nasty stuff grew in it over the course of just 2 weeks.