TIME also has a bit to do with fermentability, at least in the first ~45 minutes of the mash. If mashing much shorter than that, like 20 minutes and then mashed out, the starches will be converted to dextrins and complex sugars, but not as much simple sugars that most yeasts are capable of eating. If I want a full bodied beer, one trick I've learned is to mash for just 20-25 minutes then immediately mash out. If I want a dry beer, then I mash for a minimum of 75 minutes at which point you're right it doesn't much affect the fermentability after that point anymore... you might still eek another point or two out of both efficiency and fermentability but it isn't much after that point, unless your crush really sucked in which case then go ahead and mash overnight. Crush has a bit to do with it all as well. My guidance above assumes a good quality crush where there is a good percentage of flour and all the kernels are broken into like 6 to 8 bits, not just in half or whatever.Didn't the folks at clawhammer do a test on length of mash and found after 20-30 min almost 90+% conversion? I know temperature has a lot to do with fermentability
But methinks we digress... isn't this thread supposed to be about yeast or something? I forgot...