Unmalted barley contains all of the enzymes which will be present in the malted barley (or wheat, rye, corn, rice, etc, etc, etc…) The malting process doesn’t create enzymes.
No sir, unmalted barley doesn't contain all the enzymes, and malting does create enzymes. Here are a few references. (Emphasis added.)
"The main objective of malting is to
produce an ample supply of enzymes that degrade starch, proteins, and other components of grain."
https://www.sciencedirect.com/topic...tive of malting,and other components of grain.
"The seed of the barley and the embryo and aleurone layer are living. After the kernel absorbs water, gibberellin is excreted as a phytohormone from the germ.
Furthermore, the signal of gibberellin leads to the production of enzymes, such as amylase, and to the synthesis of β‐glucanase to decompose starch."
https://www.intechopen.com/chapters/56077
"Enzymes are present in mature barley (Beta-amylase and carboxypetidases),
finished malt (
Alpha-amylase, limit dexrinase, proteases, glucanases, pentosanases) and yeast"
https://www.mbaa.com/districts/Ontario/Events/Documents/2014 MBAA Aleksandar Egi Malt Enzymes.pdf
“During malting, hydration of the kernel starts at the basal end. The embryo and husk absorb water more readily than the endosperm. As the embryo hydrates, it releases hormones (including gibberellins), which awaken the scutellum and aleurone layer, causing them to produce their own enzymes and begin breaking down the endosperm. This process of modification starts adjacent to the scutellum at the basal end and proceeds toward the distal end.
As it reacts, the aleurone layer creates beta glucanases, protein proteases,
alpha amylase, and glucoamylase.”
Malt, A Practical Guide from Field to Brewhouse, page 95. John Mallet, 2014
"The aleurone layer acts as a hotspot for
enzyme synthesis during germination, when aleurone proteins are degraded and used to produce enzymes."
KU Leuven Certificate Course, Beer: The Science of Brewing, Module 2, Malt
"During steeping, water is taken up by barley kernels in three different phases:
PHASE 1: Water is taken up by the embryo and scutellum, initiating the production of
amylases (mostly α- amylases), ribonucleases and phosphatases."
KU Leuven Certificate Course, Beer: The Science of Brewing, Module 2, Malt