The thread already pretty much covers it. But they take base malt and then roast it until it gets to 20L; the longer you roast malt and the higher the temperature you do it at, the more you degrade the enzymes until you don't have any enzymes any more.
You see the same thing with Munich malts, but, and I'm doing this from memory so I could be wrong, with munich Malts you're still starting with "Green" malt and you jump ramp up the temperature at the end of the drying cycle. If you look at the DP rating vs. Lovibond color ratings for Briess's Munich malts, you'll see at 10L the Munich malt still has a DP of 30 (minimum to self-convert with a 100% grist in 1 hour) and by the time you get to 20L Munich, you're down to a DP of 15. -The Biscuit / Aromatic / Amber / Brown /Black malts are dry-roasted so I'd imagine at the same temps and time they denature even faster, too.
Adam