This is the only time I've roasted the same coffee to a bunch of different roast levels at the same time. I have a pH meter, but I didn't think about doing that. It's not obvious to me that pH is really what my mouth is detecting, but it might be.
Most of the coffee that I brew is not dark roast, and I'm certain (I drink a lot of coffee) that none of it is objectionably acidic. But although I want to make a science of all this coffee stuff, I'm also roasting for sustenance, so there are many times when I roast just to get through the next week, and the spectrometer and the pH meter aren't a part of the process