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One way to guestimate alkalinity is a simple aquarium test, about $5 at Walmart. It won't give you everything you need (calcium, sulfate, calcium chloride, sodium) but I use it to see if my RO water filter is working properly. One drop from the reagent confirms that it is. You can try that- but your mash pH of 8 is immaterial as it could simply have absorbed CO2 by the water sitting out.
Guestimate? IME those drop tests are pretty reliable. As you mentioned they are cheap and also very easy to use. Actually I don't really unterstand why they aren't more popular among homebrewers. They are more valuable than a pH-meter, IMHO, which I do also have, but could almost do without in the meantime. Those tests have become an essential part of my brewing water adjustements, because my water supply is extremely variable with respect to hardness/alkalinity (they blend water from two sources with starkly different profiles). Needless to say, a single water analysis/report would be totally useless in my case (and I suspect I am not the only one in the world who is getting tap water with variable chemical profiles). Given that I did not want to go the distilled/RO water route, I now measure the alkalinity of my water with one of those drop tests before each brew day. I've seen alkalinity values ranging between 150 and 260 ppm, and everything inbetween. Then I plug the value in my calculator (Bru'n Water), and I'll know exactly how much acid I need to add to achieve a given target mash pH. I was able to hit my mash pH ballpark very consistently even with those extremely variable starting alkalinity values. So I concluded than both the alkalinity tests and the water calculator must be pretty accurate.