Thanks, Yooper.
Generally, do experienced home brewers adjust their water beyond the Ph to emphasize certain minerals? Is there any tangible benefit (i.e. raising the sulfate levels produces a better IPA)?
Yes. And no.
What I mean is this- you want enough of the minerals for proper pH and yeast health. The "flavor" ions may or may not be adjusted, to taste. I'm finding that a much lower sulfate amount that in the "pale ale" profiles actually gives me better results. It's true that some sulfate enhances bitterness, while chloride provides a "fuller, rounder" beer. But I'm finding that a fairly low amount of both (along with lower alkalinity from diluting with RO water) gives me repeatable and wonderful results!
A typical water profile for me (I make primarily IPAs and APAS) looks like this:
Calcium-87 Magnesium-16 Sodium-5 Chloride-59 Sulfate-86 mash pH 5.45
As I said, I make hoppy beers 3 out of 4 times I brew, maybe more, and I'm really finding that "less is more". If you want to go with a good IPA water profile, you could try Mosher's ideal pale ale profile, but probably skip Burtonizing. Lots and lots of brewers target a "pale ale profile" with great results, and I wouldn't discount that at all. It's just been my experience is that the less a water profile is manipulated, the better the beer!
In addition, chalk doesn't dissolve anyway in the mash water properly without extraneous measures. But if you want to give it a try, maybe scale down the amounts, and try adding it to your water and see how it tastes. If you LIKE the taste of sodium bicarb and chalk in water, maybe you'd like it added to your beer. I don't.