I'm a total compost newbie, but very fascinated. I made some this summer with some yard waste and I'm guessing it was too high in nitrogen because it gave off a bit of an ammonia smell. Would spent grain be considered a "brown" contribution? How successful would composting the spent grain alone be? If not, what are some examples of common items that could be added to help and in what amounts?
Yes, spent grain is mostly a carbon contribution to the pile. This is good as your carbon/nitrogen ratio appears to be a bit too low if you were getting ammonia fumes.
I do not recommend composting the spent grain alone. There will be some sugars retained in the grain. What can happen is that a pile of wet spent grain will usually be very dense and it will be lacking in the oxygen required for aerobic bacteria to flourish. Additionally, the spent grain will usually have some sugars remaining. The combination of the lack of oxygen and the sugars can lead to a dominance of anaerobic bacteria. These can produce some horrendous odors. Think rotting corpse smell. It can be really bad. So, what you want to do is mix the spent grain into the pile so it does not compact into a single anaerobic lump. You can also spread it out over the pile which is what I usually do when I'm too lazy to mix it in.