scinerd3000
Well-Known Member
alton brown is awesome- anyone who wants to know anything nerdy about cooking should watch him- nice post of the vids...props 
I tend to dissagree. Maillard browning happens at a much lower temperature and most brewers confuse this with caramelization. You can get caramelization at the surface of your pot where the liquid touches it if the temperature is hot enough and the sugars remain on the surface long enough.
To quote the website I linked to earlier:
"Maillard reactions have three basic phases. 1/The initial reaction is the condensation of an amino acid with a simple sugar, which loses a molecule of water to form N-substituted aldosylamine. This is unstable and undergoes the famous "Amadori rearrangement" to form "1-amino-1-deoxy-2-ketoses" (known as "ketosamines") which can undergo complex subsequent dehydration, fission and polymerization reactions.
But wait, I here you say! "A sugar loses a water molecule and undergoes further dehydration?" Sounds like a Caramelisation reaction?
*And it is!* One of the reasons Caramel and Maillard reactions are confused in brewing and food processing literature is that one of the Maillard paths is a simple Caramel reaction, catalysed by amino acids."
Like the Maillard reaction, caramelization is a type of non-enzymatic browning. However, unlike the Maillard reaction, caramelization is pyrolysis, as opposed to reaction with amino acids.
Pyrolysis of carbohydrates(including sugars, starch, and fibre) and proteins requires temperatures substantially higher than 100 °C (212 °F), so pyrolysis does not occur as long as free water is present, e.g., in boiling food not even in a pressure cooker. When heated in the presence of water, carbohydrates and proteins suffer gradual hydrolysis rather than pyrolysis. Indeed, for most foods, pyrolysis is usually confined to the outer layers of food, and begins only after those layers have dried out.
Controlled pyrolysis of sugars starting at 170 °C (338 °F) produces caramel.
Caramelization of Maltose sugars occurs at 356F
You don't need a cast iron pan to caramelize sugars.
Do you know at what temperature sugars caramelize?
So, do you know at what temperature sugars caramelize?
Sorry, didn't mean to come off that way. Just wondering at what temperature sugars in food caramelize.
Hmmm...what are the different types of sugars and why would they caramelize at different temperatures?
Like the Maillard reaction, caramelization is a type of non-enzymatic browning. However, unlike the Maillard reaction, caramelization is pyrolysis, as opposed to reaction with amino acids.
Pyrolysis of carbohydrates(including sugars, starch, and fibre) and proteins requires temperatures substantially higher than 100 °C (212 °F), so pyrolysis does not occur as long as free water is present, e.g., in boiling food not even in a pressure cooker. When heated in the presence of water, carbohydrates and proteins suffer gradual hydrolysis rather than pyrolysis. Indeed, for most foods, pyrolysis is usually confined to the outer layers of food, and begins only after those layers have dried out.
Controlled pyrolysis of sugars starting at 170 °C (338 °F) produces caramel.
Caramelization of Maltose sugars occurs at 356F
If you knew all that, why did you ask about caramelization temperatures? Are you arguing that in any cooked food there is 0% caramelization? You've said yourself that pyrolysis happens on the outer layers of food, so I don't understand what your point or, is why you've bolded your text where you did.
"The Maillard Reaction" is not one specific reaction, but a combination of several different reactions, one of which is "dehydration and further oxidation and degradation."
Caramelization is defined as "dehydration and further degradation and oxidation. "
If you knew all that, why did you ask about caramelization temperatures? Are you arguing that in any cooked food there is 0% caramelization? You've said yourself that pyrolysis happens on the outer layers of food, so I don't understand what your point or, is why you've bolded your text where you did.
"The Maillard Reaction" is not one specific reaction, but a combination of several different reactions, one of which is "dehydration and further oxidation and degradation."
Caramelization is defined as "dehydration and further degradation and oxidation. "
this poster doesnt know anything... its copied form wikipedia...
I disagree. Sometimes it's difficult to put into words what you mean. So you find it on the net and copy and paste what you mean.
The poster is very knowledgeable.
i was talking about you! you copied all that from wiki... im not downing anyone. this thread got ridiculous and was just point it out.
And thank you for taking it completely 100% off topic.
Another really good tip is that if you are cooking steaks, or chops or swhatnot that will be either grilled or pan fried, it is good to let it sit out on the counter for 30-45 minutes prior to cooking. It will make for a much more consistent cook throughout.
Sorry, if someone already meantioned this but we got off topic for a while and I couldn't keep track.
Asked the wife about that one. She said she'll do that with any big hunk of meat, if she has time.
Another really good tip is that if you are cooking steaks, or chops or swhatnot that will be either grilled or pan fried, it is good to let it sit out on the counter for 30-45 minutes prior to cooking. It will make for a much more consistent cook throughout.
Sorry, if someone already meantioned this but we got off topic for a while and I couldn't keep track.
IMO, leaving meat out for 30 min or whatever depends greatly on the thickness of the steak and how hot you intend to cook it. I put the spurs to it via cast-iron skillet (handed down from my Grandma to my Mom to me). If the steak isn't thick enough and the pan isn't quite hot enough the steak will either be overcooked or won't have a nice crust.
Myth: Browning meat 'seals in the juices'. Bull**** it does no such thing, but browned meat tastes better.
Myth: Turning meat (steak/burgers) frequently is bad, you should only flip it once. Bull****, it actually cooks faster and more evenly when flipped frequently.
IMO, using high-smoke-point oil for steaks is better because the pan needs to be REALLY hot. Save the steak butter for after it's done.
FWIW, that perfect steaks article posted earlier says letting steaks sit out, salted, for between 0-40 minutes is the worst...it should be either longer or not at all. But I think there is a major flaw of that article and it is imo, a BIG key to getting a great sear/crust: the meat must be dry...totally dry when put into the pan. They were saying the extra water (pulled out with the salt) takes time to evaporate. NO, you must dry the meat with paper towels thoroughly before going into the pan.
From this past weekend:
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you can buy a high-quality (Lodge), brand new, cast iron pan for like $20!
IMO, using high-smoke-point oil for steaks is better because the pan needs to be REALLY hot. Save the steak butter for after it's done.
Exactly. You can caramelize food in a pan you have in your cubbard. You don't have to go spend $20 on a new pan.
Use the $20 towards a good instant read thermometer like a Thermapen Then you can learn to cook to a temperature rather than a time.
Exactly. You can caramelize food in a pan you have in your cubbard. You don't have to go spend $20 on a new pan.
Use the $20 towards a good instant read thermometer like a Thermapen Then you can learn to cook to a temperature rather than a time.
+1. And even different cuts feel different; a ribeye, strip, and filet will all feel a bit different but I don't think a thermometer is needed for steak/chops/chicken pieces, just the big hunks of meat. Even when using a thermo you still have to account for carryover heat.That reminds me of another tip. Learn to cook by feel not time or temp. Poking something repeatedly with a termo is going to cause it is lose a lot of juice and get dry.
Wehn you gently push meat with your finger it has a different resistence and spring based on how far it has cooked. Best way to learn is to actually. Make a bunch of kabobs. As they are cooking give one of the meat cubes a little squeeze and pay attention to how it feels. Then pull it off and cut it open and see what it is at. then let them cook a little longer and try it with another cube.
This also shows how it should feel.
http://www.youtube.com/watch?v=tk4ji3wRKsc
It does take a while to learn and while you are learning it is good to use a thermo but it is very rare that I will pull out an instant thermo for steaks or chops or chicken pieces or anything anymore.
Crap you will never see a line cook or chef using: a thermometer. Unless you are making candy or smoking pork, the thermometer stays in the drawer. If you can't tell that it is done.... well...
SpanishCastleAle said:2888426 Even when using a thermo you still have to account for carryover heat.
That reminds me of another tip. Learn to cook by feel not time or temp. Poking something repeatedly with a termo is going to cause it is lose a lot of juice and get dry.
...or get frisky with the SWMBO!Those pepper oils can be a pain in the ass to wash out. Anyone that has cut pepper sans gloves and gone to bathroom afterwards knows that.