So quick follow up. After reading lots here I determined that it's probably not needed to passivate my new SS Brewtech brew bucket, but also that it couldn't hurt. So I went for it.
I saved a bit of money by filling old milk jugs and pop bottles with water, but leaving a little air, so that they floated. This reduced how much acid solution I needed. Thanks for the tip! (NOTE: using an old cork to close a 2L pop bottle, filled with cold water.. then apply heat to 80c.. wasn't very smart. POP boom! almost hit my head!!).
After deep cleaning my old kettle and new fermenter with TSP and a soft cloth, I heated some water to 80c, added my citric acid to make a 4% solution, and did a 2 hour soak. Then put it back in the kettle, re-heated, and soaked again. Let them dry, and placed in the open air for a full day to let the oxygen get at it. Also, while doing dishes I noticed a rust spot on an old stainless kitchen bowl, so I scrubbed it well, and tossed it in to.. just in case it helps
I can't honestly say I see any visual difference. But on close inspection of the new fermenter, I see some machining chuff marks (very light). Also, some small pitting around where the external handles were welded on... some how it impacted the inside of the fermenter. So, I felt better about having done the passivation process, as at the least, it may add an oxide later to give some protection.
FWIW, my water did turn a /little/ yellow/orange. Not as much as I saw in pictures, but it was there. So it perhaps took out some iron for me.