The thing I find confusing about botulism food safety is the notion that freezing food is not enough to keep it safe. It seems like any food which is frozen and used immediately after defrosting should be safe.
I realize the spores survive boiling and freezing but I would not expect them to multiply in the freezer.
Pasteurize wort, freeze wort, defrost wort, add yeast -- where is the bacterial amplification step occurring in that sequence? That does not seem to incur any more risk than adding DME to water, boiling, cooling, adding yeast, and keeping it warm. In each case your starter could have spores present. Why is the trip to the freezer adding risk?