not sure where you go this process, but if it works awesome. To me it looks like you took 2 options for adding pecans (or any nut that has natural oils in it) to beer and combined them.
no idea the purpose of the salt water soak, i havent seen or heard of that being mentioned before, but all those processes are designed for mostly 1 thing... getting the oil out of the nut so it doesnt end up in your beer and ruin head retention or give an oily mouthfeel.
heating them releases oils (come to think of it, maybe the saltwater soak would help with this too??), oil floats, so when you dump off the salt water and vodka you are getting rid of some of the oil. Not all of it though.
Vodka is usually used as an extracting agent, not a rinse though. People will leave the nuts soaking in vodka for a few weeks then dump the whole thing into the secondary. Some even freeze the vodka mix as the oil floating on top should solidify a little making it easier to remove. I can always taste the vodka when i do anything like this and add the vodka to the beer so i dont.
My way of processing them is heating them several times (325 for 15 min each time) and vaccum sealing them in brown paper bags to extract the oils. Then crush them and add that to the mash. there is no right or wrong way to do this so as long as you dont have a head retention problem, and you are getting the pecan character you want, you are good!
However, from what i have read, most people that have done it both ways, prefer the mash method as opposed to the secondary method for flavor and lack of head retention issues.
EDIT:
just did a littel research on soaking the nuts and apparently it IS a thing, BUT, not sure we need to do it as after we get tis enzymatic process going, you are baking them.
http://foodmatters.tv/articles-1/the-benefits-of-soaking-nuts-and-seeds
Kinda sounds like something you want happening IN your mash but i am gonna read further on it. Gonna read up a bit more on it.