I am fairly new to brewing and decided to do some 1 gallon batches to try out 4 different hops with the same wort. After I did the first couple of batches I was stunned at the water loss. I had used the percentage I used for 5 gal batches. But that percentage was not close in this case and I was left with ½ gal when I was expecting a gallon. That got me thinking that the amount of water that boils off is a constant for a specific brew pot.
After reading the many answers on this subject I was still left not really understanding what is going on with the amount of water that boils away when I brew. I was going to say evaporation but it turns out in science there is a difference in evaporation and boiling. We are not losing water through evaporation when in the boil. It also turns out that water temperate is the same for a simmer vs. a rolling boil. Closer you are to sea level the hotter your boil is going to be. Now the article talked about more heat the boil would be faster, like a rolling boil, but the article did not address if you lose more water at a rolling boil than a simmer.
I found a high school science write up on the subject which shed a lot of light. It also got me thinking how much altitude plays into boil time. Based on the fact that water boils at lower temperatures in altitude you might have to boil your hops longer to get the same IBU as someone who is down at sea level.
I am going to look to see if I can find a formula that provides an answer as I am sure one exists. If I find I will post. AT the bottom in quotes is the article write up I found.
The one thing that is clear is you should get the same amount of water loss using the same pot, and I am guessing the same heat resulting the same boil profile (rolling to simmer) no matter what the volume of wort you are boiling. Thus using a percentage is incorrect. Baselining your equipment boil off, keeping the heat the same, should provide a constant volume loss for planning purposes.
“As the temperature of the water increases, its vapor pressure increases. When the vapor pressure equals the atmospheric pressure on the liquid, the liquid will boil. At high altitudes, the boiling point of liquids is lower than at sea level. In Denver, Colorado, water will boil at about 94°C. Do not confuse boiling with cooking. Cooking pasta in Denver is a slower process because the water is at a lower temperature. Also, realize that water boiling rapidly is no hotter than water boiling slowly. The temperature of the water remains constant during the boiling process. And, the temperature of a boiling liquid never rises above its boiling point. No matter how much heat is applied, the liquid only boils faster, not hotter.
There are fundamental differences between evaporation and boiling. Evaporation occurs at temperatures lower than the boiling point of the liquid. Also, evaporation occurs at the surface of the liquid, whereas in boiling, bubbles of vapor arise inside the body of the liquid. For a bubble to form, the pressure of the atmosphere on the surface of the liquid must be overcome."
Added:
After researching some physics sites it is obvious there are a lot of variables in play. BTU output being applied, atmospheric pressure (including height from sea level), wind, ambient temperature, pot metallurgy and thickness, pot diameter.
To calculate it would change for each boil based on weather. I think the key is to figure out your heat source to get a consistent boil the way you want it. I prefer rolling boil. Then do a baseline on your pot with water. I chose to use a sick and mark the differences from start, boil start, completion of 1 hr. boil, cooled 80 degrees F. Then I used a volume equation to measure the actual boil off and shrinkage after boil off to 80F. I have a Blichmann Boilermaker 10 Gal. Using the measurements I calculated the following 0.72 gal of boil off then 0.24 for the shinkage from boiling to 80F. So basically 1 gal. So now I am going to test with a boil where I would like to have 1 gal of wort. Based on previous results the 1 gal of extra water sounds correct.
I live in Southern California near sea level (850 ft). Our temperatures are fairly consistant year round. If I wanted to get fancy I could baseline and measure barometric pressure and ambient temperature. Then as I brew I could see how those variables affect the outcome. Right now I am assuming they will not have a lot of affect and holding the BTUs being applied to get a consistent rolling boil is the variable I really want to control. IF I don’t get reasonable consistency I will look at other variables. But I know why many experienced brewers take wort sugar readings to determine if they need to continue boiling or have boiled too much and need to add water.