Ph does have something to do with it, but temperature does as well. I found this after a 2 second google search, I'm trying to avoid a pissing contest.
Article states Ph has something to do with it, but read on to find:
"Temperature also affects tannin extraction. This relationship is pretty simple. If you dont want to run the risk of getting too much tannin in your wort, keep the temperature just below 170° F."
http://byo.com/stories/issue/item/1...me--reducing-tannins-but-not-flavor-mr-wizard
Well, there's what you read, and there's what you experience. And as pointed out above, if it was about temp, decoction mashes couldn't be done.