Actually no, FG = gravity at the end of fermentation. Before bottling. Then when you add a known quantity of sugar for priming, the change (less than half a percent) of ABV can be calculated.
You'll get close enough, but I would make this a one-time exception. As a habit, take FG at the end of fermentation.
HOWEVER, you can also get close enough by assuming that FG is about 75% of OG. Typical yeast under typical conditions have an average 75% attenuation rate. There might be a 5-6% varience on that attenuation, but that only equates to a few tenths of a point of ABV either way, so you can get close enough.
I haven't taken a FG reading in over two years, but then again I don't care if my beer is 5.7% ABV or 5.9% ABV as long as I know it tastes good and will give me a buzzzzzz
I just do 2-3 week primaries and have enough experience to know what it looks like when a fermentation is having an issues that needs attention, which is rare.
If you do it from the bottle, you have to make sure the beer is flat. open it, let it sit for a while- overnight- and make sure there is NO carbonation. Carbonation will give you a fasle reading.
+1 for carbonation messing up your reading. The bubbles can stick to your hydrometer after bottle conditioning giving you a higher FG than what it actually is.