What advice are you looking for? It seems like you already have a decent idea. I have not looked closely enough at all of the BJCP styles to figure out if you could actually make two different styles of beer merely by making changes post boil. I'm guessing that you will not be able to make two different accepted "styles" of beer doing this because the vast majority of the profile of the beer will already be set (the grain bill, IBU, color, and hop flavor will be set). You can split batches to test different yeasts (e.g., to see which yeast you like best for a style) or to make very different beers based on yeast selection. The other thing you could do, as kh54s10 noted, is test out different additions that are typically made during secondary fermentation.
EDIT: I should add that we can't really tell you what yeasts to try or what additions to try. There is no way for us to know what yeast profiles you like and don't like (e.g., I do not like Belgian yeast flavors), so any suggestion we make could easily include a suggestion that you will certainly not like.