It seems to me it would be too difficult. I would find another way to seal the top for the mean time and get the right size stopper. Maybe plastic wrap or aluminum foil.
As kh54s10 said (twice), your best bet would be to get the right size. They come in a slew of sizes.
If you do need to cut it down before you can get to the homebrew shop, I would suggest using a razor knife with anew blade. It's going to be nearly impossible to get it perfectly round though.