pressure is effected by temp, that vapor phase chart is perfect. co2 exists in liquid form in the tank. as long as thier is liquid left, it will have pressure, based on that chart! end of story. Only other thing that effects pressure is when you use the co2, the vapor phasing of the liquid to gas requires heat. so as you use the gas, the tank will get colder (and thus reduce the tank pressure.)
Since tank pressure even at 50° is about 600 psi and our regs are set for less than 30 psi most of the time, pressure is not an issue.
Once you run out of liquid, all you have left is tank pressure which will go down very fast, if you see your tank pressure at less than vapor pressure, its empty.
Its worth noting, that the gauge tells you pressure only! It does not tell you how much is left in the tank.