With a refractometer you don't have to take a six ounce sample, wait for it to cool, then get your reading.... you simply take a spoon, scoop a small amount of wort from the mash tun or brew kettle, drop the very small sample onto the refractometer, close it, then get your gravity reading. You may have to set it down on the counter for a couple of minutes to allow it to cool for the best reading, but... still.. a very small sample that you don't have to cool.
Having said that... I used to take a six ounce sample from the brew kettle after sparging, wait for it to cool, take the reading with my hydrometer, then pour the sample back into the boiling brew kettle.
The comparison is this... with a refractometer, I take several readings directly from the mash tun throughout the process... I take a reading from the brew kettle right after sparging. Take several readings during the boil so that I can get as close to original gravity as possible. Take a reading while I'm cooling the wort if I want to, or after cooling the wort - and before moving it to the fermenter.
The hydrometer is used for taking readings from the fermenter, and after fermentation is complete to get my final gravity reading.
I like the hydrometer, but waste too much wort, or don't get all of the readings during the brewing process that I want.