The liner is the catch. And yes, I mean beer bottles.. maybe even hand selected "good ones"....
I suppose experiment #1 would be to put a couple of caps in the oven at 250F for an hour. Check the liners. Most plastics can handle 250F.. what might happen here is that the seal goes on the bottle though because it becomes too soft.
I've sanitized bottles in the oven already with 100% success, but StarSan is a lot easier... I ran out that day.. did what I could..

Soda Glass is perfectly fine at 250F if you don't thermally shock.
Experiment #2 then would be to try this with water. I'd put the bottles in a bowl or kettle in the oven in case they did pop.
Experiment #3 then would be to try with 1.040 wort... and then check it 4 weeks later.. see if anything has soured, gravity changed, pH changed... etc...
The amount of O2 in the neck of the bottle.. eh.. I'd take my chances with that.. really it's not going to be much. I could purge with CO2, but I don't even know if it's worth it... Cardboard flavored starter beer would probably improve the flavor..
But I have to admit I've been using dry because it's hard to plan on which weekend I can brew and then it's even harder to have an hour on a weeknight for me.. so, something like canned wort is a great idea.. I like my beers at at least 1.055 and won't pay $16 for two vials.. so it's been dry yeast so far.. I'm finally doing it right with liquid yeast and a starter and it's been a PITA because I don't have the time during the week to do it..
I have frozen boiled (and I boil again) wort in quart mason jars, and except when I filled over the neck on one, it's worked okay.. even in that case it cracked the jar I was able to safely peel away the pieces and use the wort.. but it takes up a lot of space in the freezer.... so I can only do a couple of those at a time... So doing something else makes sense..
I just don't know if getting a canning rig is worth it though for the 8-9 brews a year I actually get to do....so that is why I'm looking at alternatives..
I am stingy enough that I'd "mini-mash" a gallon or so of Rahr 2-row for starters... but I have to do that in my "free" time...
I suppose that is what they make $4.50/lb DME for...sigh...