Just wondering if people have experience using Magnesium sulfate to raise sulfates rather than gypsum (calcium sulfate)? I can get plenty of MgSO4 from work for free.
Yes, you can do that. But keep the magnesium down to under about 25/26 ppm. Over that, it has a bit of a sour flavor impact, and at 40 ppm or more it can get quite disagreeable.
Brewing salts cost so little, and used in such small amounts, that I wouldn't worry about switching things up just to save $.10. Mg at high levels is a laxative, just so you know.
Epsom salt is OK for adding sulfate, but you can't add too much before the magnesium content is excessive. I find that its useful in hop focused beers.