Robert65
Major Obvious (recently promoted)
Let's revisit the "no rinse" bleach formula promoted by Charlie Talley (inventor of Star San) and others.
The no rinse formula gets away with just 80 ppm sodium hypochlorite by acidification to a pH of 5.0. At this pH, virtually all of the free chlorine is in the form of hypochlorous acid, which is the form which actually does the job.
Normally, one needs a concentration of at least 200 ppm sodium hypochlorite in order to have an effective sanitizer, assuming higher pH in plain tap water, to ensure a sufficient concentration of hypochlorous acid.
It is below pH 5.0 that chlorine gas begins to evolve, so this acidification must be carried out carefully.
Now, regarding the 1/3 cup per gallon recommendation. This is far above 200 ppm sodium hypochlorite. And since acidification to pH 6.5 is not sufficient either to significantly increase the concentration of hypochlorous acid (which is already quite sufficient,) nor to produce chlorine gas, it would seem to me that such acidification is not necessarily dangerous, but rather superfluous. So why chance it?
The no rinse formula gets away with just 80 ppm sodium hypochlorite by acidification to a pH of 5.0. At this pH, virtually all of the free chlorine is in the form of hypochlorous acid, which is the form which actually does the job.
Normally, one needs a concentration of at least 200 ppm sodium hypochlorite in order to have an effective sanitizer, assuming higher pH in plain tap water, to ensure a sufficient concentration of hypochlorous acid.
It is below pH 5.0 that chlorine gas begins to evolve, so this acidification must be carried out carefully.
Now, regarding the 1/3 cup per gallon recommendation. This is far above 200 ppm sodium hypochlorite. And since acidification to pH 6.5 is not sufficient either to significantly increase the concentration of hypochlorous acid (which is already quite sufficient,) nor to produce chlorine gas, it would seem to me that such acidification is not necessarily dangerous, but rather superfluous. So why chance it?