I would just think it's availability and cost, as others have mentioned above. Besides my LHBS, I have two other restaurant supply stores where I could go to get Food grade buckets if I needed to. The one square version they do offer, is almost twice the cost of the basic round bucket.
If they were cheaper or a few just landed in my lap for free, I'd probably use them. For me it's a case of don't fix what ain't broken. Round ones work perfectly well, so I don't see the need to go out of my way to try and find something different that probably won't work as well. Mainly for cleaning. I like the lack of corners when it comes to trying to get a vessel clean.
As also mentioned, pressure wise, you are a lot better off with a round bucket. Not that anyone ferments under pressure in a plastic bucket, but in the off chance you had a clog in the airlock, the round bucket would probably just lose the lid, where I would think a square bucket could have the possibility of cracking the bucket as easily as just blowing off the lid.