In the past I've always discarded the water that the chips soaked in. There's still plenty of character for them to contribute. I've also put them in a veggie steamer and steamed them for 15 minutes.
I have never boiled them. I just rinse the dust off and put them in the carboy in a hops bag.
Is this for sanitary reasons? I am assuming these are the pre-toasted chips, if that is the case.
Or is there a benefit to leaching them before using them? I have only used the untoasted chips and toasted them myself immediately before addition, but have never boiled them.
Do you really want to add vodka to your mead? I just bag, rinse, and add. The alcohol in the mead will extract what you want from the oak just fine.
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