it will be really close, but the different volumes you have from the difference in boiloff amount will give you slightly different hop utilization. the difference will be the greatest at the start of the boil like weirdboy said, so your initial additions would be the most effected.
how much of a difference you would actually see is probably very small, though. if you arent trying to replicate a recipe to the letter (like for a competition or something), just doubling the ingredients is good enough. if you were trying to scale from, say, a 5 gallon batch size to several bbls, especially if brewing commercially or for a competition, you would definately want to factor in the differences.