Ohhhhh-oh-oh it's magic, you know. Never believe it's not so.
I think it is impossible to read this without singing it to yourself...
Ohhhhh-oh-oh it's magic, you know. Never believe it's not so.
http://www.brewingtechniques.com/library/backissues/issue1.2/fix.html This to me suggest that yeast is suspension are much better at cleaning anything up and that early flocculation limits diacetyl removal. Hey I learned something! I had not ever considered the importance of flocculation in diacetyl levels.Highly flocculent yeast usually behave much like W-308 and can leave perceptible levels of diacetyl in beer, which is one reason why most commercial yeast strains are powdery and fully flocculate only after chilling
Point taken. I guess what most people are saying is that the idea that yeast play a roll in maturation is not a perception. It is a well accepted fact. The references I gave support this.
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Well, perhaps I am using terminology wrong, but I have always understood "metabolism" to be a blanket term referring to intracellular activity related to energy production, including various redox reactions. Wikipedia, at least, seems to agree.
Wouldn't saying "It's not metabolism, is reduction" be like saying "I'm not making beer, I'm making a Belgian Wit"?
In any case, this is semantics. The broader question was whether diacetyl, etc., can be broken down in meaningful quantities the absence of yeast, and you don't seem to be disagreeing with me on that.
Just found this from Fix
Fix said:Highly flocculent yeast usually behave much like W-308 and can leave perceptible levels of diacetyl in beer, which is one reason why most commercial yeast strains are powdery and fully flocculate only after chilling
http://www.brewingtechniques.com/library/backissues/issue1.2/fix.html This to me suggest that yeast is suspension are much better at cleaning anything up and that early flocculation limits diacetyl removal. Hey I learned something! I had not ever considered the importance of flocculation in diacetyl levels.
I haven't seen the book and I plan to buy it sometime but right now it is too expensive
Does Briggs have actual published references for the part where he describes the yeast playing a significant role after fermentation is completed during the stationary phase?
Would you mind to share those references so see if I can track them down?
If he did not referenced it, it's still just perception I'm afraid. It doesn't change much my opinion but I take your points into consideration. Thanks.
ayoungrad said:He did. Check out my link earlier to the google book pages.
I can't get the final google page to load that lists the relevant references from the reference that I linked. But that is the start of the chain leading back to the earliest references. Just like in Nature, Briggs references earlier works that reference earlier works, etc.
Briggs:
"Frequent causes of inability to control the concentration of vicinal diketones in beer are yeast of the wrong strain or yeast in poor health perhaps accelerated by the too rapid onset of fermenter cooling, causing the yeast to seperate. If active yeast is not present diacetyl will not be reduced."
Can you tell I have the day off today??
Gotcha! Thanks. But I'm interested to know if his book specifically addresses the yeast effects under starvation after maximum attenuation is reached and SG can change no longer.
I'll see if I find the book in my local libraries. I have been surprised with what they have sometimes!
This has me thinking then that we have a lot more control over diacetyl levels than we (at least I) had been thinking.
If one is using a highly flocculant strain and want low diacetyl, then once fermentations slows a little, it might be worth it to rouse the yeast a bit (I spin my carboy) to promote better breakdown of diacetyl. I often spin my carboys, to keep the yeast up and active, with the goal of getting full attentuation. Without realizing it, I was helping to reduce diacetyl as well.
Of course one can also then limit diacetyl, through yeast strain selection, opting for a less flocculant one.
Then if you want more diacetyl for certain styles, do the opposite of above and consider a cold crash as soon as your desired FG is reached.
Cool, more techniques for the toolbox.
No your terminology is correct my point is that it is the enyzmatic reduction and not yeast per se. It certainly could happen outside of a yeast cell in a number of ways.
Normally yeast are involved but then normally beer has yeast in it, doesn't it?
Maybe it is me, but I read this as yeast that has settled aren't good at removing diacetyl. This would argue against those who say that leaving the yeast on the cake helps to clean up - at least diacetyl. The yeast cake has little to do with it. Leaving the beer in the fermenter will help reduce diacetyl, but not because of the yeast cake.
Also then, transferring to a secondary will not result in a decreased ability to remove diacetyl
ayoungrad said:As far as what after maximum attenuation... his discussion of diacetyl, etc is fairly limited but it is in the section on maturation which is described to follow primary fermentation.
Maybe it is me, but I read this as yeast that has settled aren't good at removing diacetyl. This would argue against those who say that leaving the yeast on the cake helps to clean up - at least diacetyl. The yeast cake has little to do with it. Leaving the beer in the fermenter will help reduce diacetyl, but not because of the yeast cake.
Also then, transferring to a secondary will not result in a decreased ability to remove diacetyl
That's how I read it too. Once yeast have settled, they can't reduce VDKs.
Every commercial brewery dumps the cone within a few days of fermentation. I would think the fact that diacetyl is much less common in commercial beer than homebrew would be enough to observe that having a big pile of yeast in the bottom of the fermentor isn't the key to reduced diacetyl.
See, the D-rest is a different history. There seems to be no reference of what exactly the yeast does after full attenuation in brewing beer. And I looked hard for it. That's why I based my theory that not much is done by the yeast after fermentation is finished based on general knowledge in yeast metabolism I found published in reliable scientific sources. I'm not saying it's the truth, just what I believe now and I will keep looking. Will hopefully start reading the book soon!
It was also brought up however that large brewers add enzymes to increaase the speed. Maybe they dont care about the yeast cake becuase they are replacing the enzymes?
Not all (not most?) commercial breweries are adding enzymes, and in any event there's no shortage of yeast in suspension.
That's how I read it too. Once yeast have settled, they can't reduce VDKs.
Every commercial brewery dumps the cone within a few days of fermentation. I would think the fact that diacetyl is much less common in commercial beer than homebrew would be enough to observe that having a big pile of yeast in the bottom of the fermentor isn't the key to reduced diacetyl.
See, the D-rest is a different history. There seems to be no reference of what exactly the yeast does after full attenuation in brewing beer. And I looked hard for it. That's why I based my theory that not much is done by the yeast after fermentation is finished based on general knowledge in yeast metabolism I found published in reliable scientific sources. I'm not saying it's the truth, just what I believe now and I will keep looking. Will hopefully start reading the book soon!
Diacetyl as a product of fermentation is more characteristic of ales than lagers. Diacetyl is produced early in the fermentation, and then most of it is reabsorbed by the yeast and reduced to flavourless compounds later on. Yeast strains differ markedly in their diacetyl reduction ability. Some ales and a few lagers (such as the famous Pilsner Urquell) contain perceptible amounts of diacetyl, but as a rule modern brewers consider it as a fault. This is because certain bacterial infections and other errors in brewing technique will increase diacetyl levels resulting in unacceptable beer aroma and flavour profile. This parameter thus serves as a quality check. However, it is important to remember that diacetyl flavour is a natural by-product of yeast fermentation, and in some beer styles it is an optional or even required flavour component in low amounts.
Maturation of beer flavour requires the presence of yeast as a catalyst. There are many methods of finishing that have the sole objective of prolonging the contact of beer with yeast after primary fermentation is completed. I want to emphasize that a diacetyl rest with most of the yeast lying at the bottom of the tank and not enough in suspension is of no use. Most lager breweries, especially those that use Weinhenstephan 308 or similar diacetyl producing yeasts employ a long diacetyl rest, in order to minimize diacetyl in the finished beer.
Method 1
If a very cold primary fermentation was used it involves allowing the beer temperature to rise from the controlled primary fermentation temperature of about 10°C to 15-18°C when the primary fermentation is coming to an end. Normally, the time is determined by the attenuation of the beer. If, for example the wort starting gravity was 1050 and the expected terminal gravity is 1010, then the diacetyl rest would be commenced when the beer has attenuated to about SG 1023 when two-thirds of the total fermentable material in the wort has been consumed. The diacetyl rest normally lasts for 48-72 hours, until primary fermentation is over and secondary fermentation is under way. At this time the temperature is lowered when the more traditional method is followed, probably 1°C per day until the lagering temperature of 0-1°C is reached.
Method 2
If a warmer primary fermentation temperature was used for ale or lager the diacetyl rest involves either lowering the beer temperature 2 or 3°C at the end of primary fermentation or keeping it constant for up to 6 days. In lager yeast strains with low diacetyl production it is common practise nowadays to employ a short diacetyl rest followed by centrifuging to remove excess yeast and then crash cooling to 0°C. When brewing ales, that should have very low diacetyl levels especially German Ales like Alt and Kölsch, the implications are to not use highly flocculent yeast and to allow an extended primary fermentation, albeit at cooler temperatures until sufficiently low diacetyl levels are reached. Yeast that settles in the cone is still removed on a daily basis.
Beer Flavors #1: Diacetyl
Modern brewing practice dictates that beer be aged on live yeast until the vast majority of AAL is converted into diacetyl. Brewers yeast, while unable to metabolize AAL, will readily absorb and break down diacetyl into relatively flavorless compounds. By giving the beer enough contact time with the active yeast, the brewer can eliminate the diacetyl. It generally takes only about two weeks of aging an ale to assure that it will have no buttery flavors
John Palmer said:My recommendation was based on the premise that (20 years ago) larger (higher gravity) beers took longer to ferment completely, and that getting the beer off the yeast reduced the risk of yeast autolysis (ie., meaty or rubbery off-flavors) and it allowed more time for flocculation and clarification, reducing the amount of yeast and trub carryover to the bottle. Twenty years ago, a homebrewed beer typically had better flavor, or perhaps less risk of off-flavors, if it was racked off the trub and clarified before bottling. Today that is not the case.
It seems to me that commercial brewers use alternative methods of maturation utilizing techniques aimed at increasing throughput. To say that they dump the cone rapidly does not infer that the beer does not need to be conditioned. It just means (as I mentioned previously) that commercial brewers do not necessarily rely on yeast to clean things up.
That's not how I interpret Briggs or the reference I posted. They both seem to indicate that the dealing with diacetyl can be accomplished at the end of primary or during maturation. There are always yeast cells present and there is always a small amount of sugar present (even after "completion" of primary fermentation).
I'm not gonna get into this stupid debate- (it's been done to death no matter what the OP thinks) anymore but there are some things out there about diacytal and long primaries, and I've posted it repeatedly..
And I agree with that! Fermentation in lagers is so much slower, full attenuation may take several weeks. There is always some residual fermentable sugar, but since its so scarce after the bulk of fermentation has passed, temperature of the wort must be elevated to re-activate the yeast. The situation in Ales is different. I believe after a while, due to the higher fermenting temps, very little if any residual fermentable sugar at all is left, then the yeast goes into dormancy, and very little yeast-specific activity occurs during the aging process.
Chill buddy. It's not the *if* this thread is asking about, its the why. I don't think anyone is arguing the benifits as much as trying to figure out the root cause.
Thank you for the information that you have posted previously. It will definitely help the discussion.
Chill buddy. It's not the *if* this thread is asking about, its the why. I don't think anyone is arguing the benifits as much as trying to figure out the root cause.
exactly. I don't see any harm in having a civil discussion intended on furthering our knowledge.
And thanks for the links!
and to everyone else involved, thanks for keeping this civil, let's keep it this way. There is much for everyone to learn about in the brewing process.
So you're saying there's NEVER been a thread that discussed or looked at the why's before THIS thread, even in the Science section? Or you just haven't bothered to look. Just about every thread looks and tries to get a handle on the why's of it....
You can't have the what without the why...I just can't see how this thread any different than the CIVIL discussions all over here already about this?
Like THIS ONE for instance.
https://www.homebrewtalk.com/f163/secondary-not-john-palmer-jamil-zainasheff-weigh-176837/
I'm just asking....
So you're saying there's NEVER been a thread that discussed or looked at the why's before THIS thread, even in the Science section? Or you just haven't bothered to look. Just about every thread looks and tries to get a handle on the why's of it....
You can't have the what without the why...I just can't see how this thread any different than the CIVIL discussions all over here already about this?
Like THIS ONE for instance.
https://www.homebrewtalk.com/f163/secondary-not-john-palmer-jamil-zainasheff-weigh-176837/
I'm just asking....There's a million civil and uncivil discussions about this, including the one that this thread spun off of, so how is this one any different?
Chill buddy. It's not the *if* this thread is asking about, its the why. I don't think anyone is arguing the benifits as much as trying to figure out the root cause.
Thank you for the information that you have posted previously. It will definitely help the discussion.
Yep, excellent point, thanks!!!
This has been a great discussion. The best here in a long while. There is no reason we should not have a civilized discussion about the technical aspects of brewing just because the experience niche here keeps feeding us the IFs but not the WHYs of the process.
With all due respect to the book authors and the experience guys out there, I have learned from you too, but experience does not mean precise knowledge.
I am a strong believer that aging is good for homebrews, but trying to learn exactly what causes it is far more clever than pushing the idea that yeasts will do the majority of the work despite of the lack of the basic component to fuel their machinery, which is sugar.
Like I said before, I have my theories but not owner of the truth by any means. I would love if somebody proves me wrong with convincing scientific support. Ask my wife about it.
I'm just getting at the fact that a lot of info that folks are demanding or saying doesn't exist (like I pointed out with the diacytl info) DOES exists and has been posted in other threads about this topic. Just because some of you haven't seen some of the "why's " answered, doesn't mean we already haven't answered them. You'd be surprised what's already been covered in the 5 years of this...especially in the Jamil discussion, you might find exactly what you're looking for or claim doesn't exist. You imply that the why's haven't been addressed, and a lot of them have.
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