Skip the moving the brew to the secondary vessel. For ales, it's completely unnecessary unless you're going to age it on something that works best off of the yeast (dry hopping doesn't qualify).
Read the instructions (as already mentioned) and get Star San to sanitize with (also already mentioned). Fill a spray bottle with Star San solution to use when you need to sanitize something that you cannot dunk into the bucket. Also, sanitize everything that will touch the wort post boil. Chill the wort as fast as you can. If you're going to use liquid yeast, dunk the packet in the Star San solution before opening it up (believe something similar is on the pack). Read up about what temperatures the yeast you're using like best (or does it's best work at). Then keep the beer fermenting in that temp range. Get a fermometer (at the very least) for your fermenter(s). Put Star San solution into the airlock after installing it into the stopper/bung in the bunghole of the fermenter. If you're using a bucket, then just shove it into the black rimmed hole in the lid.
Depending on the yeast, and how much headspace you have, look into what you need to do to make a blow-off tube assembly. Make sure you get an OG reading of the brew before pitching the yeast. Make sure you have a hydrometer and practice using it a couple of times before brew-day.
Look up the threads about fermenting beer. There's a TON of information on the boards ready to be had. Biggest thing is to NOT rush the brew.
Just remember, RDWHAHB and time/patience is the best ally/tool you can have. Also, use the search feature of these boards. Chances are, pretty much any question you might have, has already been asked, and answered many times.