Yes, the SRM list is maintained in the database so you can add or remove colors.if it would be possible to add colors or SRM values
from the terminal run
sudo mysql
use <DATABASE NAME> (replace with your database name default is raspberrypints)
insert into srmRgb (srm, rgb ) VALUES(99,'255,0,0');
exit
this will add red at the end of the SRM list, you can change the order by changing 99 to -1 to get it on top
you can change 2550,0 to whatever RGB color you want
Maybe I will add an SRM screen to help with this