Well, I am going to guess one of two things happened:
1. After boiling and topping off with water, you didn't mix thoroughly and drew the hydro sample off the top. Since the wort is heavier, a thinner mixture would be at the top. If this is what happened, no big deal because the yeast will mix everything thoroughly during fermentation.
2. Your efficiency on your mash was low. This could happen for any number of reasons. Mash temp too high or too low, too little water, too short of mash time, poor mixing of the grains. If you used Deathbrewer's method, I would assume that you used 2 gallons of water for mash then 2 gallons for sparge. But to lose 1.5 gallons of water for only 4 lbs of grain seems extreme. I've never lost more than 1/2 gallon for 4-5 lbs.
To calculate efficiency you can use the method that Palmer explains
here in How To Brew.