One of your biggest areas of concern is keeping the pH of your mash in check to avoid extracting tannins and phenols and to maximize enzymatic activity. You also want to check your wort pH as mash pH impacts things such as protein coagulation, maillard reactions, and hop utilization. There are a lot of different ranges that different things work at during the boil so its not like you need to adjust your mash pH per se; however, it is a good note if you really want to know what's going on and to replicate your recipe exactingly. I don't because I don't care that much, but if I were brewing for a living I probably would take such notes.