I keg with sankey's and fill using a modified keg coupler. Basically I fill until it runs out the gas port. Thus, no air left, and also no headspace. I have tried naturally carbing with priming sugar with minimal success. I just bought a dual regulator and some kore couplers and am now force carbing with another co2 tank. I set the psi to 32 and let it sit for two weeks at room temp. After chilling and serving, there was very little carbonation. It's a porter, so not too big a deal his time, but will kegs carb up properly with zero headspace? Or do I just need longer than two weeks?