I've reached a point in my brewing knowledge where I'm confused about unfermentable/residual sugars...
For my last brew, a Belgian Blond, I mashed at 154 in order to try to create some residual/unfermentable sugars. The recipe software said I would hit 1.012 FG, but instead all the sugar fermented out and I hit 1.000. Not a huge problem to have -- my Blond became a Tripel! But I don't understand what happened to the unfermentable sugars?
The Belgian yeasts (I blended 3) were supposed to be moderately attenuative, but certainly not 100%.
Here are some factors that I think likely contributed to the 1.000, but I still don't understand what happened to the unfermentable sugars:
1. I tend to blend yeasts and it's very possible I overpitched. (I didn't use a pitching calculator.) Can overpitching alone cause 100% attenuation?
2. I mashed at 154, but for 90 minutes. The long mash likely created a more fermentable wort as the temp dropped a few degrees, but 100% fermentable?
3. I used a pound of table sugar to thin out the body and add ABV. (It was included in the recipe calculator.) I know sugar ferments out 100%, but again, what happened to the unfermentable sugars? Does sugar somehow accelerate fermentation so much that the yeast eats up the unfermentable sugar too?
Of course, I do know what to try next time, and I could do experiments: I could mash even higher, use less yeast, less sugar, and a shorter mash. But I want to understand what's going on, so I can better control my numbers. Thanks for any help you could provide.
I'm answering your questions without reading anybody else's responses yet.
1. Which yeasts? (Hopefully someone else already asked.) The specific strains matter a LOT. Some are probably diastaticus, hence your high attenuation. Pitch rate and overpitching does NOT matter AT ALL.
2. Your mash temperature of 154 F is not very hot. If you want low fermentability, try like 158 F. Or even 160 F. Mash TIME is the overriding factor anyway. If you had mashed for just 30 minutes instead of 90 minutes, huge difference in attenuation. Also, your 100% attenuation is specifically "apparent" attenuation, not real attenuation. In reality, there's still sugars left even at 1.000. If nearly all of the sugars actually fermented out, you would be left with a gravity closer to like 0.990. Yes, seriously.
3. The sugar definitely affected attenuation. There are still some unfermented sugars, as mentioned above in #2. Just not as much as you expected. Sugar doesn't boost the yeast or anything like that. They just see it and eat it all, up to their alcohol tolerance anyway, which in this case was apparently not reached for at least one of the three yeasts you used.
I think diastaticus was at play here. Diastaticus variant yeasts are well known for producing FG of 1.000-1.002. Belle Saison and Wyeast 3711 are the most famous of these. Yeast matters most.
Next time mash at around 156 F for just 30-40 minutes, and avoid diastaticus. You'll get a different result. But the diastaticus yeast is key. If you still have diastaticus in there, you'll still get about 1.002 no matter what the heck you do with mash time or temperature.
Now I'll read everybody else's answers, and add editorial comments as appropriate. Hope some of us are singing the same song already. Cheers.