The recommendations to use less sugar when naturally carbonating a keg then when bottling are nonsense. A keg is just a big bottle. The ratio of headspace to beer in a full keg and a properly filled bottle is virtually the same (about 6%.) Using less sugar in a keg will just give you less carbonation than you intended. However, after long enough on CO2 for serving, the carb level eventually reach the target level.
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No, it's not nonsense. Have you tried carbonating in a keg with the same amount as you'd use for bottles? I have, and it didn't work (way over-carbonated). I now use a bit more than half the bottle amount. Maybe it's because the headspace in the keg is already pressurised (i.e. effectively zero headspace)?
The recommendations to use less sugar when naturally carbonating a keg then when bottling are nonsense. A keg is just a big bottle. The ratio of headspace to beer in a full keg and a properly filled bottle is virtually the same (about 6%.) Using less sugar in a keg will just give you less carbonation than you intended. However, after long enough on CO2 for serving, the carb level eventually reach the target level.
Brew on
Ignorance is bliss!
A fixed amount of sugar will create a fixed amount of CO2 when completely fermented. 1 oz of table sugar (sucrose) will create 0.5143 oz of CO2. 1 oz of corn sugar (dextrose mono hydrate) will create 0.4441 oz of CO2. Doesn't mater whether the beer containing the sugar is in a keg or bottle.
At the completion of fermentation, beer at 65˚ - 68˚F will contain about 0.8 volumes of CO2. Cold crashing after fermentation will not significantly increase the CO2 concentration in the beer. To carbonate to 2.5 volumes, you need to add enough sugar to create (2.5 - 0.8) = 1.7 volumes of additional CO2. 1 volume of CO2 is equal to 1.9768 g/L or 0.26396 oz/gal. To create 1.7 volumes of carb, you need to create:
1.7 * 0.26396 oz/gal = 0.44873 oz/gal of CO2
To create 0.44873 oz-CO2/gal, you need to add:
0.44873 oz-CO2/gal / 0.5143 oz-CO2/oz-sucrose = 0.8725 oz-sucrose/gal
Now some of the generated CO2 will escape into the headspace in the package during carbonation. Since the headspace volume in a bottle with 12 oz of beer or a keg with 5 gal of beer in it is about 6% of the beer volume in either case (I measured both cases), the percent of the CO2 escaping from the beer into the headspace will be the same in either case, and the volumes of CO2 in the beer will be the same. The preceding is true as long as the keg headspace was not purged and pressurized with CO2.
So, what happens if you purge the headspace and pressurize to 30 psi (gauge pressure)? In that case the headspace will contain about:
((30 psi + 14.7 psi) / 14.7 psi) * (273.15˚K / 277.59˚K) = 3.0 volumes of CO2
The first term above corrects for gauge pressure vs. absolute pressure, and the second term corrects for the temps of the CO2 (assumed to be 40˚F.) So, the headspace would contain about 3 volumes of CO2 immediately after pressurizing. Most of this CO2 will dissolve into the beer, and the volumes of CO2 contributed to the beer is calculated approximately as:
0.06 * 3 volumes / 1.06 = 0.17 volumes
Thus in the case of pre-pressurized headspace, the beer would have about 0.17 volumes more carb than desired, and you would have 2.67 volumes instead of the intended 2.5. I don't think many people would consider this "way over-carbonated." So, instead of adding enough sugar to create 1.7 volumes, we only want to add enough to create:
1.7 volumes - 0.17 volumes = 1.53 volumes
Then we want to use:
1.53 / 1.7 = 0.90 => 90% of the sugar we would use in bottling.
This is a far cry from using only 50% (or even 75%) when kegging.
So, if you pre-pressurize to 30 psi when naturally carbonating a keg, you should use about 90% of the priming sugar that you would use for bottling.
Show me where I'm wrong.
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