I think what you're saying is that if you start with 2 gal and boil off 0.9 gal, then you'd assume a 7-gal boil will also boil off 0.9 gal. I'm not sure that's true, due to the vagaries of heat transfer. But assuming it were, then you'd tell BS that the Evap Rate is 0.9/7 = 13%.
Simpler and more accurate is to just assume 15% then measure pre- and post-boil volumes during your next batch in order to refine the number. Done.
No, I don't think you want to do that. You want to go through this procedure for your boil kettle because each boil kettle will have a different boil off rate, mostly due to different surface areas between kettles.
It's true that if you boiled the same amount of water on 2 different days you would likely end up with slightly different boil off amounts, due to temperature and humidity, but that doesn't mean you should guess and just fudge your number in the software. It's a simple procedure to measure your boil off one time with water and use that in BeerSmith. No reason not to do it.