I have been playing around trying to make my own recipe on beer calculus... when I use a larger boil volume the bitterness goes through the roof.. why do ou get so much more bitterness with the same batch size but a larger boil? Meaning if I boil 3 gallons then top up to 5 gallons I get like 32 IBU...same recipe but a 6.5 gallon boil is over twice the UBU's?