I'm finding that my refractometer (an Ebay one w/ only a Brix scale) does not match my hydrometer. Today I calibrated both with DO water. For a beer with an estimated OG of 1.058 my refactometer read 1.053, the hydrometer 1.057. This was at 72 degrees F. I tried the measurement multiple times, with both, and got the same results each time. I have no idea why there is a difference but my trust is leaning towards the hydromter.
Nothing wrong with your refractometer.
I have never used a hydrometer except to get the Brix correction factor.
Refractometers are calibrated to read sucrose not maltose.
You need to run a few simple tests to get the offset for maltose, a onetime deal.
To read during and after fermentations requires a different offset.
Info from Promash
Brix Correction Factor:
A Brix refractometer reading is based on the known values for percentage sucrose solutions. However, wort contains many substances other than sucrose, and many of them have different refractive indices than sucrose. For this reason, it is necessary to use a correction factor to convert from a Brix refractometer reading of raw wort to the actual gravity of the wort. The literature suggests this factor is between 1.02 and 1.06, with 1.04 often used as a default value.
To determine your own, brewery-specific Brix correction factor:
(1) Take a hydrometer sample of unfermented wort.
(2) Measure its gravity with the most accurate, calibrated hydrometer you have. Do not forget to do the temperature offset calculations. (Alternative: use a digital density meter or pycnometer -- the idea here is to get a very accurate measurement of the actual SG / Plato of the sample.)
(3) Convert this value to Plato if you measured in SG.
(4) Using a zeroed refractometer, take the refractometer reading of the same sample.
(5) Convert this value to Brix if measured in RI or Zeiss units.
(6) Brix correction factor = Refractometer reading (in Brix) / Measured Gravity (in Plato) E.g., Refractometer reading = 13.1 Brix Measured gravity = 12.7 Plato Brix Correction factor = 1.0315
(7) Do this with several different samples and average the results. The literature suggests that the value should be consistent within a particular brewhouse.
Cheers,
ClaudiusB