As EricCSU stated, Mrmalty is a great resource for all things starter related. I have done a little research on pitching starters. Mr Malty suggest pitching at high kreausen (18-24 hours after preparing the starter) which is normally what I attempt to do, however, for larger starters you may have to "step-them-up" which would mean you either have to have a container large enough to continually add wort "step-ups" to reach the desired wort volume for the amount of yeast, or chill and decant the wort from starters in a smaller vessel and then add fresh wort to increase yeast population.
It is ideal to have the correct size vessel to continue adding wort to, simply because chilling and decanting off wort in a smaller vessel and then adding fresh wort will not have the exact same effect. Yeast population requires a certain amount of room. For example, if you were to have say a 2 liter container and make a 2 liter starter then chilled and decanted of the spent wort, then added 2 liters of fresh wort, you would not have the same yeast population as if you were to have a 5 liter container, and "stepped-up" the starter wort from 2 liters to 4 liters. Once again, it has to do with space, yeast need a certain amount of space to reach a particular population.
Using the 2 liter container and chilling, decanting, and adding fresh wort will definitely increase the yeast population, just not as effeciently as when using a larger container, and of course the yeast population cannot be maximized as well.
As far as pitching at high kraeusen or chilling and decanting goes, I think both have their benefits and drawbacks. The argument can be made that pitching at high krauesen means you are pitching all of the starter wort which may contain off-flavors due to the warmer fermentation temperatures of the starter. Remember starters are for growing healthy yeast, not for making good beer, having said that, pitching 1-2 liters of starter wort into ~19 liters (5 gal) of wort will have a negligeable impact on flavor, and if you practice the "extended primary" technique where you leave the wort in the priamry for 3-4 weeks, many of the possible off-flavors created during fermentation as well as from the starter will be cleaned up to an extent by the yeasties.
As for chilling and decanting, the benefit is that when yeast go dormant they store up energy (glycogen reserves) which prepares them for the next fermentation. Glycogen reserves are a source of energy for the yeast which helps during the initial phase of fermentation (reproduction) and affects the cells ability to uptake nutrients. Which means that the yeast will have a little more fuel during the aerobic phase before fermentation begins.
Yet, pitching at high kreausen means the yeast are in action and already rockin, which reduces lag times, either way I don't necessarily think that one technique is better than another. As I stated earlier, arguments can be made for and against both, but either will work just fine. You may run into a situation where your starter has been growing for 48 hours and brew day is going to be pushed back a week or two, obviously the logical thing to do is place that starter in the fridge, and when brew day does fianlly arrive decant off the wort, and allow the slurry to reach room temps before pitching it.
Sorry for the winded response, hope this info helps.