Short answer - no
Longer answer - I guess it could depend on your grinder. The point of a grain mill is to crack open the grain. We want to expose as much of the endosperm as possible while keeping the hull as intact as possible. Thats why grain mills have 1, 2, 3 or 4 rollers that progressively crush the kernels between them. Coffee grinders on the other hand GRIND, not CRUSH. Blade grinders are obviously the worst. They just use a blade to pummel what ever is inside to oblivion. The only exception is chocolate or roasted barley. People will use a coffee grinder to grind a few oz of these black malts to add late in the mash so they dont extract too much of the acrid burnt flavors from the malt. Burr and Conical Burr grinders would be hit or miss. I don't think you would get a good crush unless you owned a $3000 + adjustable conical burr grinder.