If you really want to add magnesium, you can use Epsom Salts. I don't because according to George Fix and several others, malt already contains sufficient magnesium for brewing purposes.
When brewing pale ales (which I do 90% of the time) I add some gypsum for the Ca and SO4, and a touch of CaCl2 to boost the chloride. If I'm brewing a lager, I use enough CaCl2 to get the Ca up to 50 ppm, and forget the gypsum.
-a.
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