Chemical Engineer here. Here's some info on PG. First, when it's food grade, it is 100% non-toxic. You can drink it, bathe in it, mix it with your food, even atomize it and breathe it in and it won't hurt you. Second - In a pure state, it freezes (or melts for that matter) at -74 F. No more, no less. As you add water, that temperature goes up.
Here are some other data points, First is the Temperature (in degrees F), the second is the % PG (the rest is water):
-60F/60%; -50F/57%; -40F/54%; -30F/50%; -20F/46%; -10F/42%; 0F/36%.
Where it gets confusing, is that often PG mixtures (especially for RV Antifreeze) will list "Burst Protection". All this means is that it will freeze, but won't expand enough to burst a copper pipe. Per the Dowfrost Information Sheet (where I'm getting all this data), a -50 F "burst protection" requires 35% PG. As you look at the freeze protection (above), you see this mixture will freeze right around 0F - so it won't work as a circulating heat transfer fluid (at the temperatures you desire).
So what should you do? What I would do is buy pure PG and mix it 50/50 with water. So where do you get pure PG? Best bet (as mentioned by a previous writer) would be an animal supply store, such as Tractor Supply. They have the Ideal brand for $20 per gallon. I THINK it's pure (but could not read their label online). I would ask. Amazon is always an alternative, although a quick search gave me a price of $37 per gallon. Could you mix it with RV Antifreeze to "richen up" the RV Antifreeze? Sure, but one final warning about RV Antifreeze, sometime is includes Ethanol. Not harmful, but not as benign as PG. (Essentially, Ethanol is Grain Alcohol.)
I hope that helps!