Though, phytase is kilned out of high modified malt. Malt is inherently acidic. Crystal and black malt are more acidic than pale, pils and lager. Mashing shouldn't begin above pH 6 or below 4.7. Wort needs to be in the pH band of the yeast being used. The pH for Ale yeast is different than Lager. A rest will stablize pH, even with high modified malt. Mash pH plays an important part when it comes to enzymatic activity. Enzymes, beta and alpha become sluggish if outside their pH band. There is data that shows pH of malt for a reason. The three hour time needed for acidulation is when a small portion of sour mash is made before hand and then used to lower main mash pH. It takes at least that long to sour up the small portion of mash at lacto temps. If water chemistry is off, acidulation of the main mash will take longer or stick at a certain pH. Decoction brewers take advantage of gradual pH reduction and use it to determine rest temps for enzymatic reasons. A unique feature of a decoction is that enzymes are taken through optimum pH and temp bands a few times. When using some acid malt along with low modified pils malt and neutral water. During the time it takes to do the decoctions, going from the acid rest through the protein rest. Mash pH reduces quite a bit. Regardless of the malt being high modified or not, pH is important.