Just siphon most of it out from under the oil, you'll be fine.
I've done all kinds of experimental wines with different ingredients and for my taste, any added sugar produces an undrinkable wine.
So start with some decent ingredients. Do you have a LHBS that brings in wine grapes/juice from the West Coast? A $60 bucket of wine grape juice comes out to about $3 a bottle. With white wine its so simple: Re-hydrate your yeast, put a funnel in a sanitized carboy, dump in half of the wine grape juice, add the yeast dump in the rest and put an airlock/stopper in the carboy. When its done fermenting, rack to another carboy and keep in a cool place for 4-6 months. It won't last long and you'll wish you'd made more. Cost is about $3 a 750 ML bottle. Red wine is a little more complicated but its not really difficult.
Most supermarkets carry an apple juice called "simply apple":
http://www.simplyorangejuice.com/product/apple
If your local stores have it, just keep an eye out for when it goes on sale. Around here it goes on sale about every 4-5 weeks.
Get 2 containers of it and ferment in a 1 gallon jug. Use Brewer's best cider house select yeast.
http://www.homebrewing.org/Cider-House-Select-Cider-Yeast-Sachet_p_5043.html
Just two ingredients: Juice and yeast.
Note you can re-pitch the yeast cake into the next batch of cider with no issues.
If you have a basement, wait till the fall and ferment down there in the low 60's.
When its done, rack it to some wine bottles and let it sit for a month or two or drink it right away depending on your taste. Its not wine strength, but you can make a decent cider beverage for less than $2 a 750 ML bottle.
Once you make that, you can branch out into fruit wines and mead. There's lots of mead, wine and cider making podcasts available to help you.