Hop utilization, mainly the amount of alpha acids that get dissolved into to wort during the boil, depend on two things: 1) The amount of time they are in the boil, and 2) The Specific Gravity (SG) of the wort in the boil.
Pretty much all recipes have the time listed of how long the hops should be in the boil (Ex: 1oz of Chinook for 60 mins, etc). But a lot of recipes, especially kits, don't take into account the SG of the wort when your adding the hops and the higher the gravity of the wort the less utilization you get. For the same recipe, if your boiling 2.5 gallons of wort and topping up with water to 5 gallons afterwards, the gravity is a LOT higher during the boil than it would be if you were boiling the entire 5 gallons at once. For example, if your making a beer that should come out with an OG of 1.040, when your done with the boil of 5 gallons you should have wort that is 1.040. However if your only boiling 2.5 gallons, you should come out with wort that is 1.080 which will be 1.040 once you had the other 2.5 gallons of water and that's a big difference in SG during the boil when you're adding the hops.
After my recent "Eureka" moment of this very subject when I was scratching my head wondering why my English Brown Ale was a lot more bitter than the extract partial boil was, I was curious and decided to let BeerSmith do the math for me and I went and changed nothing but the boil volume on that extract recipe and came out with the following:
2.5 Gallon Boil: 17.1 IBUs
6.8 Gallon Boil: 29.8 IBUs
Yeah, that made me go
My current system I do a full boil and start with the ~6.8 gallons to end up with 5. This using the EXACT SAME recipe and this caused the IBU's to be 12.7 higher than what they are doing a 2.5 gallon boil. That's a big enough that you can REALLY taste the difference.
So, back to your question. Yes, you can make adjustments on the amount of hops you use if the recipe you're making is for a partial boil and you're doing a full boil. Unfortunately, it's sometimes hard to know how much to adjust if the recipe doesn't list it's boil size and/or IBUs. A lot of recipes will list those two stats on them, but a lot of others and especially kits often won't. So you're left guessing on it.
My advice would be to plug the recipe into your favorite brewing software, and look and see if it appears to be out of whack for that style. If so, adjust the hops until it seems right to you.
Or if you like to crunch the numbers yourself, there are charts on hop utilization. That and much more on the topic can be found on John Palmer's site here:
http://www.howtobrew.com/section1/chapter5-5.html