My father-in-law has threatened to lead the roof seam on his 67 Cougar, but fortunately it ended up not needing it. Plus, he would have only did it to be accurate in the restoration. He decided also to not do a strict restore, and has often mentioned how the modern fillers are so much better than they used to be.
Anyway, if you want to knock the dent out, I recommend getting a fairly heavy piece of metal on the outside, and tap carefully with a hammer (body hammer if you got one) on the inside. This would require removing the inner door panel and etc.
Then again, if you just want to fill and paint it, first use sandpaper to sand the rust completely. Then use a product like Eastwoods rust converter, which is basically an acid that converts the rust to a protective layer. THEN apply the body filler, in several light coats if necessary.
Use a modern body filler, heavyweight to start if the dent is deep. Once it has been filled you need to sand it down well, until it's just below the level of the metal (barely feel the difference with your hand). Then switch to a lightweight filler like "Icing". This will sand easier and give you a better feel for when the spot is getting close.
Then paint with an automotive primer. Once the primer has cured, lightly spray a "guide coat" on it. Just a dusting of a contrasting color which will wear off as you sand. This will help you see where there are any high or low spots.
Repeat the primer until the guide coats sand evenly. Then finish with a color close to the original, and then top with a clearcoat. When that is fully cured you can rub with compound and polish to match the orange peel from the factory.
For quick and dirty, just sand with sandpaper, spray with a sealer paint, then automotive primer and then a color close to the original. I'd paint the whole panel to help make it less noticeable.