If it's an aluminum kettle, you need to boil water in order to set the passive oxide layer or whatever it is called, so you might as well kill two birds with one stone and measure your boiloff rate. If it's SS it's not necessary to set the layer than you can just brew your first batch of beer and measure. The thing about it is that, if you are decent in your effieciency and hit your pre-boil gravity, if your boiloff is higher than you anticipate your gravity will be off just the right amount that topping off to your final volume will bring it to the right og. If you have too much then you either can leave it behind, try to jam it in the fermenter and use a boiloff tube, or put it in another container (like a gallon jug) and ferment that.