From everything I have read doing the very dark malts is nearly impossible at home since they are so close to being charred.
If you really just had to give it a shot I would use an air-pop popcorn machine. I use one for roasting coffee and it does a pretty good job of it. The circulating air ensures an even toast and it allows you to keep an eye on things as you go. Once they hit the color you want quickly dump them into a metal strainer and toss to cool.
That said, I would just go ahead with the 300L, and use a bit more, it won’t be exactly the same, but it should still be tasty.
Edit: Another option is to use black patent, I find it very similar to 500L roast barley. Maybe a combo of it with the 300L barley. Something to think about anyway.