The "older" tanks, the steel ones that are refereed to as 20cf. for oxygen and 5 lb. for Co2 service are the same tanks. The tanks have different valves and burst disks (pressure safety device) due to there different operating pressures.
The industrial O2 valve is a CGA (Compressed Gas Association) 540 and the Co2 valve is a CGA 320.
If you have an "old" O2 tank it can be converted or exchanged at most welding supply shops. If it is out of test (10 years on O2 5 years on Co2) you will more than likely have to pay for the re-certification (hydrostatic test) for the cylinder.