Well, I lose more than 19% between the start of the boil, and ending up in the fermenter, but it's not all evaporation.
The loss is caused by a combination of:
Evaporation
Hop absorption
Shrinkage caused by cooling
Wort trapped in the CFC
Dead space in the kettle.
For Beersmith to function correctly, it should be able to calculate the hop absorption and cooling, but you have to tell it the amount trapped in the CFC and kettle dead space as well as some means of estimating the evaporation.
If you put it all down to evaporation, it will interfere with the algorithms used by Beersmith to predict the final volume, and produce inconsistent results for different beers.
-a.