I agree and disagree with what you fellows are establishing.
First:
Well, if the recipe is already pretty well established, I don't see why you wouldn't do a 5g batch with your tweaks. As long as you don't go insane, I don't think you would mess it up much.
Truth. Adding a smidge of this and a tetch of that ain't gonna mess it up TOO badly. See my above comment about beer and pizza.
This, however:
I was also thinking along the lines of getting better technique as well, hoping that 1g batches would help me become a better brewer as well as allow room for experimentation.
...I cannot condone. Brewing a skintillion different recipes or merely brewing more often will not, I say again NOT, make you a better brewer; it'll make you a brewer who's brewed a lot, which is by no means the same thing. I know brewers who brew twice a week who can't brew their way out of a paper bag. At the same time, I know brewers who brew once a month who are awe-inspiring masters of their craft.
Brewing the same recipe (or small stable of recipes) over and over, until you get the technique and skills of brewing 100% down pat, until you can get consistent results over and over again, now
that will make you a better brewer. In order to properly learn something, remove variables. Then put variables back in.
Like this: Pick a simple recipe you like. Single-infusion, let's say SMaSH ale. Brew that until you think you've got it consistent, until you're getting blind-taste results from other people (NOT YOU) who think you keep giving them bottles from the same batch. Cool. You've learned how to brew that recipe well. Now say you want to learn about how Munich malt impacts a recipe. Brew the SMaSH, but sub in Munich for 20% of the grist.
See what I mean?
Moreover, there are dynamics and issues with batch size that impact equipment, which impacts technique. A 1 gallon grist in the same mash tun in which you brew 5 gallon batches will have totally different dynamics than a 5-gallon mash. If you're using different equipment, you're deliberately placing an obstacle in learning your craft. Neither situation is helpful in improving your skills: in the former, you're using a screwdriver as a chisel, and in the latter you're learning nothing about how to use the screwdriver because you're using the chisel.
Doing something different each time you brew isn't mastering your craft. It's playing around. Let me be abundantly clear: If that's what you want,
THAT'S PERFECTLY OKAY. However, you appear to have an ambition of becoming a better brewer. Playing around isn't going to accomplish that.
Totally forgot about yeast, too. Properly pitching a 1 gallon brew length using readily-available commercial packaging is damn near impossible. You're almost always going to be overpitching, which is not the "Ahhh, forget about it" thing most people seem to have in their heads. Pitching the right amount of yeast is as important as any other ingredient.* For good pitching on the 1-gallon scale, you're going to be forced to pitch slurry.
Cheers,
Bob
* It will never cease to amaze me that some of the same people who will obsess over malt analyses and how many grams of hops to add at what time during the boil will just dump in any old amount of yeast and call it a day.