Check into Sub Noir. I don't know where they have their beer on tap and I've never been to the brewery, but sometimes they have things that look very interesting. I'd skip Lonerider and Big Boss and hit up breweries that aren't really distributing like Raleigh Brewing (don't think they're distributing far (if at all) the RTP, BruePrint (lame name but pretty solid beer specifically the scotch ale), and a few others I named in our previous PM. If you want to hit up a bottle shop then The Beer Dispensary has great selection. They're small so they don't have everything but their selection is quite nice and the atmosphere is wonderful. If you find your way past Smithfield, you must hit Double Barley. Hands down.
Back to Asheville, I mentioned Wicked Weed and LAB, Highland is great, Green Man for sure, and Pisgah, which is in Black Mountain, I think. If there may as well keep on and get to Oskar. They open early
unlike other breweries in Asheville.